Browsing by Author "Kuznetsov, Vitaliy N."
Now showing 1 - 2 of 2
Results Per Page
Sort Options
Item Quantum-Mechanical Modeling of the Interaction between Carbon Nanostructures and Metal Ions(Pleiades Publishing, Ltd, 2021) Tytarenko, Valentyna V.; Shtapenko, Eduard P.; Voronkov, Eugene O.; Zabludovsky, Volodymyr O.; Kolodziejczyk, Wojciech; Kapusta, Karina; Kuznetsov, Vitaliy N.EN: In order to investigate a deposition mechanism, authors have proposed a set of quantum chemical models for formation of fullerene C60 and single-wall carbon nanotubes (SWNTs) C48 metal complexes with Co, Ni, Cu, and Zn. Obtained results proving that adsorption of Co, Ni, Cu, Zn ions on a surface of fullerene C60 and SWNT C48 from the aqueous solution of electrolytes is possible with formation of stable metal-doped carbon nanoparticle complexes. Minimum energy complexes of C60-Co and C60-Cu have corresponded to the structure where ion is located above the center of C6 cell. Meanwhile, C60-Ni complex reach a minimum energy when ion is above the middle of a C-C bond, and for C60-Zn complex the most stable conformation is the one when ion is upon the carbon atom. All the optimized structure for metal complexes with C48 has shown ions been located above the C6 cell’s center.Item Track Circuits Adjusting Calculation Method Under Current Influence Traction Interference and Electromagnetic Compatibility(IOP Publishing, 2020) Razgonov, S. A.; Kuznetsov, Vitaliy N.; Zvonareva, Olga V.; Chernikov, D.EN: The problem of railway transport electromagnetic compatibility automation systems in recent years has been aggravated by the use of power frequency converters in electric transport drives, which significantly increase the efficiency of traction characteristics of 3-phase electric engine. However, estimate relevant harmonic levels in the frequency range used in track circuits of railway automation and telemechanic systems. The paper provides theoretical justification for practical measurements of interference. It is shown, that the interference coefficients monotonically increase in the following cases: 1) increase in the value of the harmonic frequency; 2) increase in the propagation constant, taking into account the supports resistance of the contact network; 3) increase in the circuits track length. Operating frequencies of tonal track circuits up to 800 Hz, the interference increase rate in given length of the rail circuit slows down. The increase in interference coefficients depending on the mentioned factors is explained by the fact that with current part growth of the harmonic flows from the traction substation through the earth increases and thereby creates currents asymmetry of the track circuits.